A novel organotin-substituted polyoxomolybdate cluster

作者：Li Shun Li; Zhang Yong Mei; Ma Jian Fang^*; Lan Ya Qian; Yang Jin

来源：Dalton Transactions, 2008, (8): 1000-1002.

DOI：10.1039/b714915h

A novel organotin-substituted polyoxomolybdate cluster (H(3)O)(16)[(H(2)O)(2)Mo(V)O(OH)](2){Mo(28)(VI)Mo(4)(II)(NO)(4)(BuSnO)(2)-[BuSn(OH)(2)](2)O(102)(H(2)O)(12)}center dot 18H(2)O 1 was synthesized in a 'one-pot' reaction by adopting the reduction-oxidation-reconstitution self-assembly process, which shows a {Mo(34)(NO)(4)Sn(4)} mixed metal skeleton, which is constructed from two {Mo(16)(NO)(2)Sn(2)} subunits being linked by two MoO(6) octahedra.

• 出版日期2008
• 单位鞍山师范学院; 东北师范大学