An unprecedented 3D POM-MOF based on (7,8)-connected twin Wells-Dawson clusters: synthesis, structure, electrocatalytic and photocatalytic properties

作者：Li, Shaobin; Zhang, Li; O'Halloran, Kevin P.; Ma, Huiyuan^*; Pang, Haijun

来源：Dalton Transactions, 2015, 44(5): 2062-2065.

DOI：10.1039/c4dt03625e

• METAL-ORGANIC FRAMEWORKS
• VISIBLE IRRADIATION
• HELICAL CHANNELS
• BUILDING UNITS
• POLYOXOMETALATE
• COMPLEXES
• TIO2
• DEGRADATION
• ADSORPTION
• EVOLUTION

The first (7,8)-connected polyoxometalate-based metal-organic framework (POM-MOF) has been constructed from seven-and eight-connected twin Wells-Dawson clusters, and possesses the highest connection number of polyoxometalates to any mixed-connected POM-MOF to date and a unique structural motif that contains both organic-inorganic and all-inorganic networks.

• 出版日期2015
• 单位黑龙江大学; 哈尔滨学院