A series of multinuclear homo- and heterometallic complexes with bridging tellurolato ligands derived from [Cp*Ir(CO)(TeTol)(2)] (Cp* = eta(5)-C5Me5, Tol = p-tolyl)

作者：Nakagawa Takafumi; Seino Hidetake; Mizobe Yasushi^*

来源：Journal of Organometallic Chemistry, 2010, 695(1): 137-144.

DOI：10.1016/j.jorganchem.2009.09.038

• Iridium
• Tellurolato complex
• Multinuclear complex
• Heterometallic complex
• X-ray crystallography

Reactions of [Cp*Ir(CO)(TeTol)(2)] (1; Tol = p-tolyl) with certain organometallic Pd(II), Pt(II), Ir(III), Rh(III), and Ru(II) species afforded IrPd, IrPt, IrPt2, Ir-2, IrRh, IrRu3, and IrRu complexes having tellurolato-bridged dinuclear or trinuclear cores. This finding demonstrates that 1 is a versatile precursor to synthesize a variety of multinuclear homo-and heterometallic mu-tellurolato complexes, whose chemistry is still less advanced as compared with that of mu-thiolato complexes.

• 出版日期2010-1-1