An Effective Diels-Alder Reaction of Vinyl Allenols with Dienophiles

作者:Choi Subin; Hwang Hoon; Lee Phil Ho*
来源:European Journal of Organic Chemistry, 2011, (7): 1351-1356.
DOI:10.1002/ejoc.201001148

摘要

Vinyl allenols obtained from reaction of aldehydes with vinyl propargyl bromide and indium underwent Diels-Alder reactions with a variety of symmetric and unsymmetric dienophiles in dichloromethane or toluene regioselectively, producing cyclohexenylmethyl alcohols possessing an exo methylene moiety in good to excellent yield.

  • 出版日期2011-3