Substrate-thickness Dependence of Hydrogenated Microcrystalline Silicon Nucleation Rate on Amorphous Silicon Layer

作者：Zuo, Zewen^*; Cui, Guanglei; Wang, Yu; Wang, Junzhuan; Pu, Lin; Shi, Yi

来源：Chemical Vapor Deposition, 2013, 19(10-12): 363-366.

DOI：10.1002/cvde.201307003

• Compressive stress
• Microcrystalline silicon
• Nucleation rate
• Strained Si-Si bonds
• Thickness dependence

The nucleation rate of hydrogenated microcrystalline silicon (mu c-Si:H) films deposited by plasma-enhanced (PE)CVD on hydrogenated amorphous silicon (a-Si:H) substrates is investigated through structural and electrical characterization, with special attention paid to the initial growth stage of mu c-Si:H films. It is found that the nucleation rate of mu c-Si is dependent on the thickness of the a-Si:H substrate. The mu c-Si:H film exhibits a rapid nucleation on a thin a-Si:H layer, leaving a thin incubation layer at the mu c-Si/substrate interface. This substrate-thickness dependence of the nucleation rate is proposed to be correlated with the stress inside the a-Si:H layer. The high interfacial stress existing in the thin a-Si:H layer facilitates the formation of high concentration, strained Si-Si bonds, which are responsible for the rapid mu c-Si nucleation. The thick a-Si:H layer relaxes the interfacial stress through the formation of islands in the Stranski-Krastanow (S-K) growth mode, while the intrinsic stress is still low, resulting in a long nucleation process allowing for the intrinsic compressive stress to be accumulated that is necessary for the mu c-Si deposited on it.

• 出版日期2013-12
• 单位南京大学; 安徽师范大学