A Copper Porphyrin for Sensing H2S in Aqueous Solution via a "Coordinative-Based" Approach

作者:Mirra Silvia; Milione Stefano; Strianese Maria*; Pellecchia Claudio
来源:European Journal of Inorganic Chemistry, 2015, 2015(13): 2272-2276.
DOI:10.1002/ejic.201500070

摘要

A turn on fluorescence-based probe for sensing H2S in water via a coordinative-based approach has been successfully devised. The probe can selectively detect H2S in aqueous solutions over other anions, biothiols, and common oxidants such as H2O2. H-1 NMR spectroscopy and ESI-MS experiments provide evidence that the turn-on response in the presence of H2S is due to binding of the target anion to the copper center.

  • 出版日期2015-5