Autoignition of ethylene in shock waves

作者:Tereza A M*; Slutskii V G; Severin E S
来源:Russian Journal of Physical Chemistry B, 2010, 4(3): 475-485.
DOI:10.1134/S1990793110030176

摘要

The delay time of ignition of various C(2)H(4)-O(2)-Ar mixtures behind reflected shock waves were measured at temperatures of 1090-1520 K and a pressure of 0.65 +/- 0.05 MPa. A kinetic scheme of the ignition of ethylene based on the known rate constants of the key elementary reactions was developed. The scheme satisfactorily describes our own and published data on the ignition of ethylene in shock waves over wide ranges of temperature (1100-2400 K), pressure (0.006-0.64 MPa) and ethylene (0.1-17.4 vol %) and oxygen (0.6-20.7 vol %) concentrations.

  • 出版日期2010-6

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