科研之友
微信
新浪微博
Facebook
分享链接
摘要
A novel strategy using polyhomologation and ring opening metathesis polymerization (ROMP) has been developed for the synthesis of well-defined polyethylene (PE) molecular brushes. Polyhomologation was used to afford an OH-terminated PE, which after transformation to the norbornyl PE macromonomer was subjected to ROMP. Kinetics of ROMP of the PE macromonomer was studied by in situ H-1 NMR monitoring. The brush structure was proved from HT-GPC, H-1 NMR and DSC results.
- 出版日期2014-11-21
