A fluorescence-enhanced chemodosimeter for Fe(3+) based on hydrolysis of bis(coumarinyl) Schiff base

作者：Lin, Weiying^*; Yuan, Lin; Feng, Jianbo; Cao, Xiaowei

来源：European Journal of Organic Chemistry, 2008, 2008(16): 2689-2692.

DOI：10.1002/ejoc.200800077

• probes
• iron
• fluorescence
• Schiff bases

Bis(coumarinyl) Schiff base I was designed and synthesized as a fluorescence turn-on chemodosimeter for Fe(3+). The chemodosimeter was readily synthesized in four steps from 2,4-dihydroxybenzaldehyde. The addition of Fe(3+) to chemodosimeter 1 induced about a 140-fold enhancement in fluorescence. Furthermore, chemorlosimeter 1 was also highly selective to Fe(3+) over other metal ions, and most of the related metals ions exhibited negligible detection interference.

• 出版日期2008-6
• 单位湖南大学