Azocalix[4]arene Strapped Calix[4]pyrrole: A Confirmable Fluoride Sensor

作者：Thiampanya Preecha; Muangsin Nongnuj; Pulpoka Buncha^*

来源：Organic Letters, 2012, 14(16): 4050-4053.

DOI：10.1021/ol301684r

A new chromogenic fluoride sensor based on 1,3-di-p-nitrophenylazocalix[4]arene-calix[4]pyrrole (1) was designed and synthesized. The color of the solution of probe 1 changed upon the addition of any F-, CH3CO2-, PhCO2-, and H2PO4- ions. However, from these ions the highly specific sensing of F- is achieved by the addition of Ca2+ which leads to a color change from light sky blue (of 1.F-) back to the original light orange color of 1.

• 出版日期2012-8-17