Access to unusual polycyclic spiro-enones from 2,2 '-bis(allyloxy)-1,1 '-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence

作者:Piedra Estefania; Francos Javier; Nebra Noel; Suarez Francisco J; Diez Josefina; Cadierno Victorio*
来源:Chemical Communications, 2011, 47(27): 7866-7868.
DOI:10.1039/c1cc11907a

摘要

Treatment of 2,2'-bis(allyloxy)-1,1'-binaphthyls with the first-generation Grubbs' carbene under MW-irradiation results in the formation of new polycyclic spiro-enones through an unprecedented RCM/Claisen sequence.

  • 出版日期2011