A mixed-valence lanthanide metal-organic framework, templated by 2,2′-bipyridine formed in situ reaction: synthesis, structure, and luminescent properties

作者：Cai, Bowei; Ren, Yanwei; Jiang, Huanfeng^*; Zheng, De; Shi, Dabin; Qian, Yuying; Chen, Jun

来源：CrystEngComm, 2012, 14(16): 5285-5288.

DOI：10.1039/c2ce25160d

• COORDINATION POLYMERS
• MICROPOROUS METAL
• POROUS MATERIAL
• CARBON-DIOXIDE
• ION-EXCHANGE
• MMX-CHAIN
• LIGAND
• NETWORK
• COMPLEXES
• TEMPERATURE

A novel lanthanide metal-organic framework, {(bpy)(0.5)[Dy-3(ip)(4)(phen)(4)(H2O)]center dot 2H(2)O}(n) has been synthesized via a hydrothermal method. Single-crystal X-ray analysis reveals that the center ions are mixed-valence Dy (II, III) and that trans-2,2'-bipyridine was formed in situ from 1,10-phenanthroline under hydrothermal conditions in the presence of Dy(III) ions.

• 出版日期2012
• 单位华南理工大学