A peanut-like Keggin-type POM-incorporated metal-organic framework

作者：Zang, Hong-Ying; Tan, Ke; Lan, Ya-Qian; Yang, Guang-Sheng; Shao, Kui-Zhan; Su, Zhong-Min^*

来源：Inorganic Chemistry Communications, 2010, 13(12): 1473-1475.

DOI：10.1016/j.inoche.2010.08.020

• Polyoxometalates
• Metal-organic cage
• Cu-II complex
• Optical band gap

A novel peanut-like POM-based metal-organic framework Cu-3(BIMB)(5)(BIM)(2)(PMo12O40)(2) has been successfully constructed. The metal-organic framework forms a peanut-like shell and {PMo12} anions embed in the voids to act as cores. The whole framework can be simplified as a (4,5)-connected 3D topology. In addition, we investigated the optical band gap of the title compound 2.84 eV.

• 出版日期2010-12
• 单位东北师范大学; 长春大学