A sigma(4), lambda(5)-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters

作者：Doux M; Mezailles N; Melaimi M; Ricard L; Le Floch P^*

来源：Chemical Communications, 2002, (15): 1566-1567.

DOI：10.1039/b203550b

A palladium(II) complex of a S-P-S pincer ligand featuring a metallated ylidic P-atom efficiently catalyzes the coupling between pinacolborane and various iodoaryls to yield the corresponding arylboronic esters (TON between 5100 and 76500).

• 出版日期2002