Stabilizing nickel-rich layered cathode materials by a high-charge cation doping strategy: zirconium-doped LiNi0.6Co0.2Mn0.2O2

作者：Schipper Florian; Dixit Mudit; Kovacheva Daniela; Talianker Michael; Haik Ortal; Grinblat Judith; Erickson Evan M; Ghanty Chandan; Major Dan T^*; Markovsky Boris^*; Aurbach Doron

来源：Journal of Materials Chemistry A, 2016, 4(41): 16073-16084.

DOI：10.1039/c6ta06740a

Ni-rich layered lithiated transition metal oxides Li[NixCoyMnz]O-2 (x + y + z = 1) are the most promising materials for positive electrodes for advanced Li-ion batteries. However, one of the drawbacks of these materials is their low intrinsic stability during prolonged cycling. In this work, we present lattice doping as a strategy to improve the structural stability and voltage fade on prolonged cycling of LiNi0.6Co0.2Mn0.2O2 (NCM-622) doped with zirconium (+ 4). It was found that LiNi0.56Zr0.04Co0.2Mn0.2O2 is stable upon galvanostatic cycling, in contrast to the undoped material, which undergoes partial structural layered-to-spinel transformation during cycling. The current study provides sub-nanoscale insight into the role of Zr4+ doping on such a transformation in Ni-rich Li[NixCoyMnz]O-2 materials by adopting a combined experimental and first-principles theory approach. A possible mechanism for a Ni-mediated layered-to-spinel transformation in Ni-rich NCMs is also proposed.

• 出版日期2016