科研之友
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摘要
Studies to convert nitroalkanes into amides and esters using I-2 and O-2 revealed in situ-generated iodine species facilitate the homolytic C-I bond cleavage of ,-diiodonitroalkanes, arguably in an autoinductive or autocatalytic manner. Consequently, we devised a rapid and economical I-2/O-2-based method to synthesise sterically hindered esters directly from primary nitroalkanes.
- 出版日期2018-6-21
