A novel 3D network constructed from tetra-substituted trisalkoxy-hexavanadate clusters: Na-2[(V6O7)-O-IV{(OCH2)(3)CNH2}(4)]

作者：Xie, Youquan; Huang, Bo; Xu, Chao; Hu, Xunliang; Chen, Weizhou; Xiao, Zicheng^*; Wu, Pingfan^*

来源：Inorganic Chemistry Communications, 2017, 84: 96-98.

DOI：10.1016/j.inoche.2017.08.010

• Polyoxovanadate
• Hydrothermal synthesis
• Crystal structure
• 3D framework
• Cyclic voltammetry

A new tetra-substituted trisalkoxy-hexavanadate Na-2[(V6O7)-O-IV{(OCH2)(3)CCH2NH2}(4)] (1) has been synthesized under hydrothermo conditions and structurally characterized by IR, TG, UV-Vis, elemental analysis and single crystal X-ray diffraction. Compound 1 exhibit a 3D network similar to the silica oxide in which each POM cluster was connected to four neighboring clusters by sodium ions, results in good thermostability. The electrochemical property of 1 was also studied by cyclic voltammetry.

• 出版日期2017-10
• 单位湖北工业大学