A novel water-rich mononuclear copper(II) complex with pyridine-2,4-dicarboxylate: Synthesis and crystal structure

作者：Tu B T^*; Zhu H L; He G; Chen Y; Hu B; Chen J Z

来源：Russian Journal of Coordination Chemistry, 2011, 37(9): 696-700.

DOI：10.1134/S1070328411080112

A new monomolecular copper(II) complex, [Cu(Phen)(2)(Pda)] center dot 9H(2)O (I) (H(2)Pda = pyridine-2,4-dicarboxylate acid, Phen = 1,10-phenanthroline), has been prepared from H(2)Pda and Phen at room temperature and characterized by IR, elemental analysis, X-ray powder diffraction, and single-crystal X-ray diffraction. Structure analysis shows that each Cu(II) is coordinated by two Phen ligands and one Pda ligand to complete a octahedron CuN(5)O chromophore. In addition, a unique water networks paralleling to (001) composed by the crystallization water through hydrogen bonds play a important role in the stability of crystal structure. The crystal structure is found to be orthorombic with space group Pbcn and cell parameters a = 13.651(4), b = 22.516(7), c = 22.386(7) , R (1) = 0.0735 and wR (2) = 0. 0.1935.

• 出版日期2011-9
• 单位中国地质大学（北京）; 宁波大学