A high performance hybrid capacitor with Li2CoPO4F cathode and activated carbon anode

作者：Karthikeyan K; Amaresh S; Kim K J; Kim S H; Chung K Y; Cho B W; Lee Y S^*

来源：Nanoscale, 2013, 5(13): 5958-5964.

DOI：10.1039/c3nr00760j

For the first time, we report the possibility of utilizing Li2CoPO4F as a novel cathode material for hybrid capacitor applications. Li2CoPO4F powders were prepared by a conventional two-step solid state method. A hybrid cell was fabricated using Li2CoPO4F as the cathode along with activated carbon (AC) as the anode in 1 M LiPF6 dissolved in 1 : 1 EC/DMC electrolyte and its electrochemical properties were examined by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and constant current charge-discharge (C-D) techniques. The Li2CoPO4F/AC cell is capable of delivering a discharge capacitance of 42 F g(-1) at 150 mA g(-1) current density within 0-3 V region having excellent coulombic efficiency of over 99% even after 1000 cycles. Furthermore, the Li2CoPO4F/AC cell exhibited excellent rate performance with an energy density of similar to 24 W h kg(-1) at 1100 mA g(-1) current and maintained about 92% of its initial value even after 30 000 C-D cycles. Electrochemical impedance spectroscopy was conducted to corroborate the results that were obtained and described.

• 出版日期2013