Mathematics of thermal diffusion in an exponential temperature field

作者：Zhang Yaqi; Bai Wenyu; Diebold Gerald J^*

来源：Chemical Physics, 2018, 505: 1-5.

DOI：10.1016/j.chemphys.2018.03.002

• Thermal diffusion
• Exponential temperature field
• Shock formation
• Distribution of density fraction

The Ludwig-Soret effect, also known as thermal diffusion, refers to the separation of gas, liquid, or solid mixtures in a temperature gradient. The motion of the components of the mixture is governed by a non-linear, partial differential equation for the density fractions. Here solutions to the nonlinear differential equation for a binary mixture are discussed for an externally imposed, exponential temperature field. The equation of motion for the separation without the effects of mass diffusion is reduced to a Hamiltonian pair from which spatial distributions of the components of the mixture are found. Analytical calculations with boundary effects included show shock formation. The results of numerical calculations of the equation of motion that include both thermal and mass diffusion are given.

• 出版日期2018-4-13