A Technique to Fabricate La2O2CN2: Tb3+ Nanofibers and Nanoribbons with the Same Morphologies as the Precursors

作者：Guo Xiaomin; Yu Wensheng; Dong Xiangting^*; Wang Jinxian; Ma Qianli; Liu Guixia; Yang Ming

来源：European Journal of Inorganic Chemistry, 2015, 2015(3): 389-396.

DOI：10.1002/ejic.201402860

• Lanthanum
• Luminescence
• Nanostructures
• Nanofibers
• Nanoribbons
• Electrospinning

Terbium(III)-doped lanthanum dioxymonocyanamide (La2O2CN2: Tb3+) nanofibers and nanoribbons were fabricated, by the cyanamidation technique, from precursor La2O3: Tb3+ nanofibers and nanoribbons prepared by electro-spinning. The morphology of the final products were the same as those of the precursors. X-ray powder diffraction analysis indicated that the crystal phase of La2O2CN2: Tb3+ is tetragonal in space group I4/mmm. SEM analysis revealed that the thickness and width of the La2O2CN2: Tb3+ nanoribbons is about 184 nm and 3.53 +/- 0.37 mu m, respectively, and the diameter of the La2O2CN2: Tb3+ nanofibers is 175.87 +/- 16.23 nm at a 95% confidence level. When excited with a 274 nm ultraviolet light source, the La2O2CN2: Tb3+ nanostructures emit predominantly at 543 nm; this emission originates from the D-5(4) -> F-7(5) energy level transition of the Tb3+ ion. It was found that the optimum molar concentration of Tb3+ ions for doping La2O2CN2: Tb3+ nanostructures is 3%. The La2O2CN2: Tb3+ nanofibers exhibit a higher photoluminescence (PL) intensity than that exhibited by nanoribbons for the same doping concentration. Commission International de l'Eclairage (CIE) analysis demonstrated that color-tuned luminescence can be obtained by changing the concentration of the doping activator ions and the nanostructure morphology. Possible formation mechanisms for the La2O2CN2: Tb3+ nanofibers and nanoribbons are also proposed. More importantly, the new technique employed in this paper and the preparation method are of universal significance for providing other rare earth oxycyanamide nanostructures with various morphologies.

• 出版日期2015-1
• 单位长春理工大学