Double layer water-borne heat insulation coatings containing hollow glass microspheres (HGMs)

作者:Zhang, Dawei*; Li, Haiyang; Qian, Hongchang; Wang, Luntao; Li, Xiaogang
来源:Pigment & Resin Technology, 2016, 45(5): 346-353.
DOI:10.1108/PRT-04-2015-0041

摘要

Purpose - This study aims to construct a double layer heat insulation coating based on hollow glass microspheres (HGMs) and to investigate the effect of particle size on barrier property and heat insulation performance. @@@ Design/methodology/approach - The waterborne double layer coating was composed of an anticorrosive epoxy ester primer and an HGM-containing silicone acrylic topcoat. With varied HGM sizes (20 mu m, 40 mu m, 60 mu m and a 1:3 w/w mixture of 20 and 60 mu m particles), the coating was immersed in 3.5 wt% NaCl solution for 28 days and was then subjected to a salt spray test for 450 h. The barrier properties of the coating were evaluated through electrochemical impedance spectroscopy. Heat insulation performance was examined using a self-made device. @@@ Findings - The addition of HGMs decreased the barrier properties of the coating by creating particle/resin interfaces for water penetration. In the HGMs-containing coatings, the use of larger HGMs showed relatively good barrier properties because of the lower particle density. The coating with smaller particles yielded a higher heat insulating capacity as indicated by lower equilibrium temperatures. @@@ Research limitations/implications - Future work will be focused on improving the barrier properties of the coating. Field exposure tests should also be performed to assess the long-term performance of the coating. @@@ Practical implications - The mechanical properties of the coatings in this study also implied that HGMs can be used to develop scratch-resistant and impact-resistant coatings. Other potential applications for further studies include the uses of HGMs for coatings with improved fire retardancy and electromagnetic interference shielding. @@@ Originality/value - A double layer coating was developed to provide balanced performance on both anticorrosion and heat insulation. The effects of HGM size were particularly highlighted.