Acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}- 1-methylethyl)pyridine]methylpalladium(II) hexafluoridoantimonate dichloromethane hemisolvate

作者：Li Liuzhong; White Peter S; Hao Aiyou^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2011, 67: M365-U784.

DOI：10.1107/S1600536811005277

In the title compound, [Pd(CH(3))(C(26)H(14)F(18)NOP)(C(2)H(3)N)][SbF(6)]center dot 0.5CH(2)Cl(2), the Pd(2+) cation has a distorted square-planar environment, being coordinated by the acetonitrile [Pd-N = 2.078 (8) angstrom] and methyl [Pd-C = 2.052 (9) angstrom] groups and the bidentate ligand 2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine (L). In L, one -CF(3) group is rotationally disordered between two orientations in a 1:1 ratio. The solvent molecule was treated as disordered between two positions related by an inversion center with occupancies fixed at 0.5. The crystal packing exhibits weak intermolecular C-H center dot center dot center dot F contacts.

• 出版日期2011-3
• 单位山东大学