A new dihydrogen phosphate selective anion receptor utilizing carbazole and indole

作者:Lee Sung Kyu; Han Yeunkun; Choi Yusun; Kang Jongmin*
来源:Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2012, 74(1-4): 177-182.
DOI:10.1007/s10847-011-0098-0

摘要

Dihydrogen phosphate selective anion receptor 2 based on one carbazole and two indole moieties was designed and synthesized. Fluorescence and H-1 NMR titration clearly showed that receptor 2 was a good sensor in the selective recognition for dihydrogen phosphate over other anions. Receptor 2 utilized two amide hydrogens, three amine hydrogens to bind anions. These five hydrogens formed concave structure for the selective recognition of dihydrogen phosphate.

  • 出版日期2012-12