Anion- interaction stitching 2-D layers formed by self-assembly of cations of a mononuclear copper(II) complex: synthesis, crystal structure and magnetism of [Cu(OAc)(2,2'-dypam)2](ClO4) [HOAc = acetic acid, 2,2'-dypam=2,2'-dipyridylamine]

作者：Choudhury Somnath Ray^*; Chen Chih Yuan; Seth Saikat; Kar Tanusree; Lee Hon Man; Colacio Enrique; Mukhopadhyay Subrata

来源：Journal of Coordination Chemistry, 2009, 62(4): 540-551.

DOI：10.1080/00958970802308359

• Anion- interaction
• Self-assembly
• 2
• 2'-Dipyridylamine
• Cu(II) complex
• Supramolecule
• Magnetism

A mononuclear Cu(II) compound [Cu(OAc)(2,2'-dypam)2](ClO4) (1), where HOAc and 2,2'-dypam are, respectively, acetic acid and 2,2'-dipyridylamine, has been synthesized and characterized by single crystal X-ray diffraction analysis. The cations of 1 link by N-H O hydrogen bonds to form infinite 1-D zig-zag chains, which run along the b axis. Two adjacent chains along the c axis are joined by C-H O hydrogen bonds to form a 2-D network. These 2-D layers are further bridged by perchlorate anions via weak anion- interactions that act as a supramolecular glue to build the 3-D supramolecular network. Variable temperature (1.7-300 K) magnetic measurements revealed very weak intermolecular antiferromagnetic interactions at temperatures below 20 K between Cu(II) ions mediated by hydrogen bonds, C-H and interactions. At temperatures 20 K, susceptibility data corresponds to isolated Cu(II) ions, indicating that the weak interactions affect the magnetism of 1 only at very low temperatures.

• 出版日期2009