Mechanics and Chemistry: Single Molecule Bond Rupture Forces Correlate with Molecular Backbone Structure

作者：Frei Michael; Aradhya Sriharsha V; Koentopp Max; Hybertsen Mark S^*; Venkataraman L

来源：Nano Letters, 2011, 11(4): 1518-1523.

DOI：10.1021/nl1042903

• Molecular conductance
• force spectroscopy
• gold point contact
• bond rupture
• break-junction

We simultaneously measure conductance and force across nanoscale junctions. A new, two-dimensional histogram technique is introduced to statistically extract bond rupture forces from a large data set of individual junction elongation traces. For the case of Au point contacts, we find a rupture force of 1.4 +/- 0.2 nN, which is in good agreement with previous measurements. We then study systematic trends for single gold metal molecule metal junctions for a series of molecules terminated with amine and pyridine linkers. For all molecules studied, single molecule junctions rupture at the Au-N bond. Selective binding of the linker group allows us to correlate the N-Au bond-rupture force to the molecular backbone. We find that the rupture force ranges from 0.8 nN for 4,4' bipyridine to 0.5 nN in 1,4 diaminobenzene. These experimental results are in excellent quantitative agreement with density functional theory based adiabatic molecular junction elongation and rupture calculations.

• 出版日期2011-4