A new colorimetric and fluorescent bifunctional probe for Cu2+ and F- ions based on perylene bisimide derivatives

作者:Wang, Yefeng; Zhang, Liang; Zhang, Guanjun; Wu, Yue; Wu, Shengying; Yu, Jianjun; Wang, Limin*
来源:Tetrahedron Letters, 2014, 55(21): 3218-3222.
DOI:10.1016/j.tetlet.2014.03.137

摘要

A perylene bisimide derivative (PBI) based calorimetric and fluorescent bifunctional probe PAM-PBI was designed and synthesized. It was highly selective and sensitive for distinguishing both Cu2+ and F- from other ions through a conspicuous change of UV-vis and fluorescence spectra. The recognition of Cu2+ by PAM-PBI showed an obvious color change from rose red to purple in aqueous solution, while the sensing of F- gave a marked color change from rose red to light green in THF.