Aromatization of hydrocarbons by oxidative dehydrogenation catalyzed by nickel porphyrin with molecular oxygen

作者：Dai, Xuan; Chen, Dongwei; Zhou, Weiyou^*; Yang, Song; Sun, Fu'an; Qian, Junfeng; He, Mingyang; Chen, Qun^*

来源：Catalysis Communications, 2018, 117: 85-89.

DOI：10.1016/j.catcom.2018.09.003

• Metalloporphyrins
• Aerobic oxidation
• Nickel complex
• Dehydroaromatization

Some metalloporphyrins (MTPPs, M = Ni, Fe, Co, and Cu) have been introduced as catalysts for the dehy-drogenative aromatization of hydrocarbons using molecular oxygen as the ultimate oxidant. The results revealed that NiTPP could efficiently catalyze the dehydroaromatization of 9,10-dihydroanthracene by O-2 to anthracene, and various substrates could be tolerated. According to the obtained results, a possible reaction pathway for the aerobic dehydrogenative aromatization of hydrocarbons under nickel porphyrin has been proposed.

• 出版日期2018-12
• 单位常州大学