Parent Anions of Iron, Manganese, and Nickel Tetraphenyl Porphyrins: Photoelectron Spectroscopy and Computations

作者：Buytendyk Allyson M; Graham Jacob D; Gould Julian; Bowen Kit H^*

来源：Journal of Physical Chemistry A, 2015, 119(32): 8643-8646.

DOI：10.1021/acs.jpca.5605175

The singly charged, parent anions of three transition metal, tetraphenyl porphyrins, M(TPP) [Fe(TPP), Mn(TPP), and Ni(TPP)], were studied by negative ion photoelectron spectroscopy. The observed (vertical) transitions from the ground state anions of these porphyrins to the various electronic states of their neutral counterparts were modeled by density functional theory computations. Our experimental and theoretical results were in good agreement.

• 出版日期2015-8-13