Discriminative detection of bivalent Mn ions by a pH-adjustable recognition method via quantum dot fluorescence sensing

作者：Xu Shuhong; Wang Chunlei; Zhang Haisheng; Sun Qingfeng; Wang Zhuyuan; Cui Yiping^*

来源：Journal of Materials Chemistry, 2012, 22(18): 9216-9221.

DOI：10.1039/c2jm00046f

In this report, we report a novel pH-controlled recognition method for the discriminative detection of Mn(II) and Cu(II) ions via CdTe QD fluorescence sensing. The detection limits of Mn(II) are 10 nmol L-1 to 5 mu mol L-1. Our results indicate that the sensitivity of QD fluorescence sensing to Mn(II) strongly depends on the solution pH, whereas the sensitivity to Cu(II) is subject to a minor impact of pH. Therefore, the recognizable detection of Mn( II) and Cu(II) can be realized by adjusting the solution pH. The discriminative detection of Cu(II) is realized under Mn(II)-insensitive pH, whereas the recognition of Mn(II) is realized after the deduction of the Cu(II) impact by measuring the sample at both Mn(II)-sensitive pH and Mn(II)-insensitive pH. The mechanism for the peculiar pH-controlled sensitivity of Mn(II) is investigated, which is attributed to the pH-dependent diffusion and adsorption of Mn(II) on the surface of 1-thioglycerol (TG)-capped CdTe QDs followed by the energy transfer from CdTe QDs to Mn(II).

• 出版日期2012
• 单位东南大学