An ultrastable, flexible POM-based coordination polymer with redox properties

作者：Luo, Yu-Hui; Lu, Xin-Xin; Zhang, Hong^*

来源：CrystEngComm, 2014, 16(34): 7865-7868.

DOI：10.1039/c4ce01123f

• METAL-ORGANIC FRAMEWORK
• BILAYER OPEN FRAMEWORK
• POLYOXOMETALATE
• LUMINESCENCE
• ADSORPTION
• SEPARATION
• STABILITY
• CHEMISTRY
• MIL-53
• ANION

A new flexible coordination polymer based on the Keggin-type structure H3PW12O40 center dot xH(2)O, [Cu(L)(2)(H2O)H(PW12O40)]center dot 7H(2)O (1), has been prepared. The framework of 1 shows dynamic behavior accompanied with the removal/adsorption of guest water molecules. Compound 1 can remain intact even in 8 mol L-1 hydrochloric acid, dilute NaOH solution (pH = 12) and boiling water.

• 出版日期2014
• 单位东北师范大学