Deposition and characterization of graded Cu(In1-xGax)Se-2 thin films by spray pyrolysis

作者：Babu B J; Velumani S^*; Kassiba A; Asomoza R; Chavez Carvayar J A; Yi Junsin

来源：Materials Chemistry and Physics, 2015, 162: 59-68.

DOI：10.1016/j.matchemphys.2015.05.001

• Chemical synthesis
• Coatings
• Electronic materials
• Thin films
• Band-structure
• Semiconductivity

Cu(In1-xGax)Se-2 (CIGS) thin films and their graded (x = 1 to 0) layer were grown on soda lime glass substrates using chemical spray pyrolysis (CSP) at different substrate temperatures (T-s). After optimization of Ts, depositions were carried out at different gallium composition (x) at optimized temperature of 350 degrees C. All the films deposited at T-s, >= 350 degrees C were polycrystalline chalcopyrite structure, with a preferential orientation of (112), including the graded layer. With increase in x, lattice parameters a and c were observed to decrease. Line scan of the CIGS layer showed intersection of gallium and indium concentrations, revealing the graded nature of the film. Composition dependence of Raman peak for CuInSe2 (CIS) deposited by CSP was analyzed. Optical transmittance at a wavelength of 800 nm of the film with x = 0 (CIS) (30%) was found lower than that of the film grown with x = 0.82 (CIGS) (50%). Cusp-shape of the resistivity was observed with an increase of x leading to steep rise in resistivity of the films (1.61-71.68 Omega-cm) till x = 0.42 and then decreased to 4.78 Omega-cm at x = 0.82. Carrier concentrations of the films were evaluated in the order of 10(16)-10(19) cm(-3) with p-type conductivity. These results indicate that graded CIGS thin films with modulated gallium composition can be prepared by CSP.

• 出版日期2015-7-15