Molecular and microstructural characterization of lecithin-based oleogels made with vegetable oil

作者：Bodenne Maxime; Guo Qing; Rousseau Derick^*

来源：RSC Advances, 2016, 6(53): 47373-47381.

DOI：10.1039/c6ra04324k

• Assembly mechanism
• Isotropic fluids
• Lattice structures
• Low concentrations
• Micro-structural characterization
• Partial phase diagram
• Small angle x-ray diffractions
• Structure and morphology

The molecular and microstructural organization of lecithin/canola oil oleogels as a function of water content, lecithin concentration and temperature were explored using rheology, polarized light microscopy, confocal microscopy and X-ray diffraction. Using a partial phase diagram, a large gel region consisting of 10-30 wt% of lecithin was formed. The range of w(o) values (molar ratio of [H2O]/[lecithin]) leading to gel formation at high lecithin concentration (30 wt%) was broader (w(o) = 0.28-2.78) than at low concentration (10 wt%) (w(o) = 1.25-1.67). Rheology results showed that the gels (w(o) = 1.40) transitioned to liquids at 50-55 degrees C regardless of lecithin concentration (10, 20 and 30 wt%). Small-angle X-ray diffraction at 25 degrees C revealed a reverse hexagonal (H-II) lattice structure with a d-spacing of 52 angstrom and liquid crystallites similar to 1200 angstrom in length that rearranged with temperature evolving towards a less-ordered isotropic fluid unable to gel. At the microscale, gels showed a 3D network composed of microfibres with an average diameter of similar to 1 mu m. The proposed self-assembly mechanism is based on the packing of reverse hexagonal tubules parallel to the axis of fibres. The gel network forms due to branching and overlapping of these bundles at junction zones along the reverse micellar chains. In conclusion, lecithin and water content underpinned the structure and morphology of these oleogels.

• 出版日期2016