摘要

Synthesis of 2,3,2',3'-tetrahydro-1H,1'H-[2,2']biindenyl 2 from the dimerization reaction of indene with lithium naphthalenide was carried out and we here report its single crystal X-ray structure. Synthesis and characterization of compounds 3-8 have also been carried out successfully. The stability of biindenyl and its stereochemistry at position 2 and 2' was investigated using density functional theory.

  • 出版日期2005-9