Atom transfer radical polymerization of methylmethacrylate mediated by a naphtyl-nickel(II) phosphane complex

作者：De Roma, Antonella; Yang, Hai-Jian; Milione, Stefano; Capacchione, Carmine; Roviello, Giuseppina; Grassi, Alfonso^*

来源：Inorganic Chemistry Communications, 2011, 14(4): 542-544.

DOI：10.1016/j.inoche.2011.01.019

• ATRP
• Nickel
• Methylmethacrylate
• Polymerization

The ATRP polymerization of styrene, p-chlorostyrene and methylmethacrylate (MMA) in the presence of the trans-chloro(naphtyl)bis(triphenylphosphane)nickel(11) complex was investigated. The polymerization of MMA is well controlled as witnessed by the narrow average molecular weight distribution of the polymer products and the linear increase of the M-n values vs. polymerization time. NMR analysis of the polymer chain ends confirmed that the ATRP mechanism is operative in the controlled polymerization of this monomer.

• 出版日期2011-4
• 单位中南民族大学