Urothermal Synthesis of a New Cd(II)-Terephthalate: Synthesis, Structure, CO2 Adsorption and Luminescent Properties

作者：Dong Yanli; Zhou Pingping; Liu Huimin^*

来源：Journal of Inorganic and Organometallic Polymers and Materials, 2014, 24(5): 874-878.

DOI：10.1007/s10904-014-0053-9

• Cd(II) compound
• Urothermal synthesis
• Inorganic chain
• Luminescence

A new Cd(II) compound, namely [Cd(pbdc)(e-urea)](n) (1 H(2)pbdc = terephthalic acid, e-urea = ethyleneurea), has been synthesized by urothermal reactions of Cd(NO3)(2), and H(2)pbdc. Single crystal X-ray analysis reveals that it features a three-dimensional framework based on Cd(II)-carboxylate inorganic chains. The coordinated e-urea molecules are filled in the rhombic channels. Thermal analysis reveals that it can be stable up to 350 A degrees C. The CO2 adsorption and luminescent properties of compound 1 were also investigated.

• 出版日期2014-9
• 单位河北农业大学