The first structurally characterized N-heterocyclic carbene complex with a ligand derived from pyrimidine

作者：Hildebrandt Bjoern; Reiss Guido; Ganter Christian^*

来源：Journal of Organometallic Chemistry, 2010, 695(3): 474-477.

DOI：10.1016/j.jorganchem.2009.10.049

• NHC
• Palladium
• Pyrimidine

Oxidative addition of N-alkyl-2-halopyrimidinium cations to [Pd(PPh(3))(4)] gives straightforward access to the cationic complexes [(PPh(3))(2)(NHC)PdX]BF(4) (3a,b) with pyrimidine-derived NHC-ligands. The new complexes were fully characterized including X-ray crystallography.

• 出版日期2010-2-1