A New Route for the Synthesis of Methylene Dibenzoate by Using An Ionic Liquid

作者:Likhanova Natalya V; Lijanova Irina V*; Morelos Alvarado Laura P; Martinez Garcia Marcos; Hernandez Ortega Simon; Olivares Xometl Octavio
来源:Current Organic Chemistry, 2013, 17(1): 79-82.

摘要

Ionic liquids are often used together with dichloromethane in different reactions. This combination can be problematic because the use of ionic liquids with a carboxylic acid as an anion and dichloromethane can lead to the formation of methylene diesters. The reaction of trioctylmethylammonium benzoate with dichloromethane was studied, where the ionic liquid acted as reactant, solvent and catalyst. The molecular structure of methylene dibenzoate was determined by X-ray crystallography.

  • 出版日期2013-1