An ester appending multifunctional ionic liquid for Pd(II) catalyzed Heck reaction

作者：Sawant Anand D; Raut Dilip G; Darvatkar Nitin B; Desai Uday V; Salunkhe Manikrao M^*

来源：Catalysis Communications, 2010, 12(4): 273-276.

DOI：10.1016/j.catcom.2010.10.004

• Heck
• IL
• Palladium
• Nanoparticles

A basic ester functionalized imidazolium based ionic liquid (IL2) 3 Methyl 1-(ethoxycarbonylmethyl) imidazolium hydroxide was designed eyeing in situ generation and stabilization of palladium nanoparticles for palladium catalyzed Heck reaction of haloarenes and olefins This phosphine-free Pd-IL catalyst demonstrated excellent activity and reusability at relatively low reaction temperature (80 C) for a wide spectrum of haloarenes including ch

• 出版日期2010-12-15