Aerosol-Assisted CVD-Grown PdO Nanoparticle-Decorated Tungsten Oxide Nanoneedles Extremely Sensitive and Selective to Hydrogen

作者：Annanouch Fatima E; Haddi Z; Ling M; Di Maggio F; Vallejos S; Vilic T; Zhu Y; Shujah T; Umek P; Bittencourt C; Blackman C; Llobet E

来源：ACS APPLIED MATERIALS %26 INTERFACES, 2016, 8(16): 10413-10421.

DOI：10.1021/acsami.6b00773

• aerosol-assisted CVD
• nanoneedles
• nanoparticles
• gas sensor

We report for the first time the successful synthesis of palladium (Pd) nanoparticle (NP)-decorated tungsten trioxide (WO3) nanoneedles (NNs) via a two-step aerosol-assisted chemical vapor deposition approach. Morphological, structural, and elemental composition analysis revealed that a Pd(acac)(2) precursor was very suitable to decorate WO3 NNs with uniform and well-dispersed PdO NPs. Gas-sensing results revealed that decoration with PdO NPs led to an ultrasensitive and selective hydrogen (H-2) gas sensor (sensor response peaks at 1670 at 500 ppm of H-2) with low operating temperature (150 degrees C). The response of decorated NNs is 755 times higher than that of bare WO3 NNs. Additionally, at a temperature near that of the ambient temperature (50 degrees C), the response of this sensor toward the same concentration of H-2 was 23, which is higher than that of some promising sensors reported in the literature. Finally, humidity measurements showed that PdO/WO3 sensors displayed low-cross-sensitivity toward water vapor, compared to bare WO3 sensors. The addition of PdO NPs helps to minimize the effect of ambient humidity on the sensor response.

• 出版日期2016-4-27