DESIGN AND SYNTHESIS OF DUMBBELL-SHAPED POSS-C-60 DYADS WITH FLEXIBLE SPACER

作者：Yang, Fafu^*; Li, Congcong; Guo, Hongyu; Ye, Jinqi; Jiao, Ziyu

来源：Synthetic Communications, 2012, 42(24): 3664-3669.

DOI：10.1080/00397911.2011.589562

• 1,3-Dipolar cycloaddition
• fullerene
• POSS
• synthesis

Using polyhedral oligomeric silsesquioxane (POSS) as starting material, novel dumbbell-shaped POSS-C-60 dyads with flexible spacers were designed and synthesized in good yields by esterification, subsequent etherification, and further 1,3-dipolar cycloaddition of azomethine ylide generated in situ from aldehyde and sarcosine to C-60.

• 出版日期2012
• 单位福建师范大学