Optical properties of thallium indium disulfide (TlInS2) single crystals

作者:Karotki A V*; Sheleg A U; Shevtsova V V; Mudryi A V; Mustafaeva S N; Kerimova E M
来源:Journal of Applied Spectroscopy, 2012, 79(3): 398-403.
DOI:10.1007/s10812-012-9614-2

摘要

Transmission, photoluminescence, and reflectance spectra of TlInS2 single crystals grown by the Bridgman-Stockbarger method were measured at 4.2 K near the fundamental absorption edge. Narrow lines at similar to 2.5535 and similar to 2.5694 eV were observed in the transmission spectrum and assigned to ground and excited free-exciton states, respectively. The free-exciton binding energy and band-gap energy Eg were found to be similar to 21.2 meV and similar to 2.5747 eV, respectively. A recombination mechanism was proposed for the TlInS2 near-band-edge and deep luminescence.

  • 出版日期2012-7

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