Aerobic Direct C-H Arylation of Nonbiased Olefins

作者:Gigant Nicolas; Backvall Jan E*
来源:Organic Letters, 2014, 16(17): 4432-4435.
DOI:10.1021/ol501924t

摘要

An efficient ligand-promoted biomimetic aerobic oxidative dehydrogenative cross-coupling between arenes and nonbiased olefins is presented. Acridine as a ligand was found to significantly enhance the rate, the yield, and the scope of the reaction under ambient oxygen pressure, providing a variety of alkenylarenes via an environmentally friendly procedure.

  • 出版日期2014-9-5