Aryne Insertion into I-I sigma-Bonds

作者:Rodriguez Lojo Diego; Cobas Agustin; Pena Diego; Perez Dolores*; Guitian Enrique
来源:Organic Letters, 2012, 14(6): 1363-1365.
DOI:10.1021/ol300439r

摘要

A new protocol for the efficient synthesis of o-diiodoarenes has been developed. This method allows the synthesis of substituted and polycyclic o-diiodoarenes, which are difficult to obtain by classical methods. This diiodination process involves the formal insertion of arynes into the I-I sigma-bond.

  • 出版日期2012-3-16