科研之友
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摘要
Aqueous solutions of ruthenium nitrosyl chloride complexes have been studied by(14)N, N-15, O-17, Ru-99, and Cl-35 NMR. Individual complex species have been identified and the corresponding chemical shifts have been determined. The primary aquation product of the pentachloronitrosylruthenate ion is the cis-[RuNO(H2O)Cl-4](-) complex, which subsequently undergoes isomerization. The equilibrium constants of interconversions of ruthenium nitrosyl chloride complexes in an aqueous solution at room temperature have been estimated.
- 出版日期2013-8
