Aqueous Phase Reforming of Glycerol Over the Pd Loaded Ni/Al2O3 Catalysts

作者:Karthikeyan Dhanapalan; Shin Gwan Su; Moon Dong Ju; Kim Jong Ho; Park Nam Cook; Kim Young Chul*
来源:Journal of Nanoscience and Nanotechnology, 2011, 11(2): 1443-1446.
DOI:10.1166/jnn.2011.3309

摘要

Bifunctional catalysts containing (0.5-1.5 wt%) palladium and 15 wt% of Nickel supported on gamma-Al2O3 were prepared via an impregnation technique and catalysts were characterzed by XRD BET surface area and SEM, respectively. The aqueous phase reforming of glycerol (APR) was conducted over alumina-supported catalysts at different reaction conditions for catalytic activity. Finally, we concluded that the 1.0 wt% Pd 15 wt% Ni/gamma-Al2O3 catalyst evidences higher conversion, hydrogen selectivity, lower alkane selectivity and CO production. This indicate that Pd loaded Ni/gamma-Al2O3 could be a potential catalyst for the APR of glycerol.

  • 出版日期2011-2

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