Dramatic Solid-State Humidity-Induced Modification of the Magnetic Coupling in a Dimeric Fluorous Copper(II)-Carboxylate Complex

作者：Motreff Artur; da Costa Rosenildo Correa; Allouchi Hassan; Duttine Mathieu; Mathoniere Corine; Duboc Carole; Vincent Jean Marc^*

来源：Inorganic Chemistry, 2009, 48(13): 5623-5625.

DOI：10.1021/ic9005218

The very fast and efficient water vapor absorption of the dimeric fluorous copper(II)-carboxylate complex [CU(2)(C(8)F(17)CO(2))(4)(acetone)(2)] (1) leads, in the solid state, to a dramatic decrease of the exchange magnetic coupling between the copper(II) ions and to a drastic change of its powder EPR spectrum.

• 出版日期2009-7-6