Development of a Co-MgO catalyst for high-pressure dry reforming of methane based on design of experiment, artificial neural network and grid search

作者：Omata K; Nukui N; Hottai T; Showa Y; Yamada M^*

来源：Journal of the Japan Petroleum Institute, 2004, 47(6): 387-393.

DOI：10.1627/jpi.47.387

• methane dry reforming
• combinatorial catalysis
• design of experiment
• artificial neural network
• grid search
• cobalt magnesia catalyst

Dry reforming of methane is a potentially important process to convert the greenhouse gases carbon dioxide and methane simultaneously to syngas (CO + H-2). The most serious problem with the dry reforming of methane is carbon deposition, so preparation parameters of the citric acid method were surveyed to prepare an active Co-MgO catalyst with low carbon deposition using design of experiment, artificial neural network and grid search. The preparation parameters such as Co loading, amount of citric acid, calcination temperature, and pelletization pressure were determined according to an L-9 orthogonal array. After 9 data sets of the parameter activity were designed and measured in a conventional pressurized fixed bed reactor, an artificial neural network was constructed. The optimum composition was determined by a grid search and verified experimentally to be active with a small amount of carbon deposition. Design of experiment combined with an artificial neural network and grid search was useful for catalyst development.

• 出版日期2004-11