Mechanocatalytic Polymerization and Cross-Linking in a Polymeric Matrix

作者:Jakobs Robert T M; Ma Shuang; Sijbesma Rint P*
来源:ACS Macro Letters, 2013, 2(7): 613-616.
DOI:10.1021/mz400201c

摘要

A latent olefin metathesis catalyst, bearing two polymeric NHC ligands, was embedded in a semicrystalline polymer matrix containing cyclic olefins. The catalyst was activated by straining the solid material under compression, resulting in polymerization and cross-linking reactions of the monomers in situ. Catalyst activation in the solid state may be employed in new self-healing materials.

  • 出版日期2013-7