A novel architecture of dandelion-like Mo2C/TiO2 heterojunction photocatalysts towards high-performance photocatalytic hydrogen production from water splitting

作者：Yue, Xinzheng; Yi, Shasha; Wang, Runwei; Zhang, Zongtao^*; Qiu, Shilun

来源：Journal of Materials Chemistry A, 2017, 5(21): 10591-10598.

DOI：10.1039/c7ta02655b

• CHARGE SEPARATION
• H-2 EVOLUTION
• TIO2 NANOTUBES
• NANOPARTICLES
• ENHANCEMENT
• COCATALYST
• GENERATION
• CDS
• ELECTROCATALYSTS
• FABRICATION

In the development of photocatalytic hydrogen (H-2) production, designing and optimizing photocatalyst nanostructures with efficient charge transfer and separation for catalytically active sites are still a great challenge. Herein, a well-controlled synthetic strategy is developed to prepare an Mo2C/TiO2 heteronanostructure, in which the TiO2 3D hierarchical configuration is loaded with highly dispersed Mo2C nanoparticles. This heterostructure achieves the excellent photocatalytic activity of 39.4 mmol h(-1) g(-1) with its rate similar to 25 times higher than that of pristine TiO2. Also, our photocatalysts process excellent long-term durability (>20 h). The impressive photocatalytic H-2 activity of Mo2C/TiO2 indicates favourable charge carrier dynamics, as determined by the results of photoluminescence (PL), time-resolved photoluminescence (TRPL), surface photovoltage (SPV), and open circuit potential (OCP) decay curves. Moreover, this study provides a guide for researchers to design new functional materials with excellent hydrogen production activity.

• 出版日期2017-6-7
• 单位吉林大学; 无机合成与制备化学国家重点实验室